A new route to cyclic urea derivatives of sugars via phosphinimines

József Kovács, István Pintér, András Messmer, Gábor Tóth, Helmut Duddeck

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Abstract

Sugar phosphinimines and the corresponding aminophosphonium salts were prepared from 2-amino-2-deoxy-d-glucosyl azide derivatives and their structures were established by 13C- and 13P-n.m.r. spectroscopy. A simple one-pot procedure, involving reaction of the azides with triphenylphosphine and carbon dioxide, provides an efficient access to cyclic urea derivatives.

Original languageEnglish
Pages (from-to)101-111
Number of pages11
JournalCarbohydrate Research
Volume166
Issue number1
DOIs
Publication statusPublished - Aug 15 1987

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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