A new family of platinum(ii) complexes incorporating five-and six-membered cyclic phosphine ligands

Andrea Kerényi, Viktória Kovács, T. Körtvélyesi, K. Ludányi, L. Drahos, G. Keglevich

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Abstract

New platinum complexes of the type cis-Pt(L)2Cl2 have been synthesized from five-and six-membered cyclic phosphines, which were prepared after deoxygenating a series of phosphine oxides (3-phospholene oxides, phospholane oxides, a 1,4-dihydrophosphinine oxide, and a 1,2,3,6- tetrahydrophosphinine oxide). The complexes were characterized by NMR and mass spectral data, and their stereostructures were elucidated by B3LYP/6-31G(d)-LANL2DZ ECP calculations. The phosphine intermediates were characterized as the corresponding phosphine-boranes.

Original languageEnglish
Pages (from-to)63-70
Number of pages8
JournalHeteroatom Chemistry
Volume21
Issue number2
DOIs
Publication statusPublished - 2010

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phosphine
Platinum
Oxides
Ligands
Phosphines
Boranes
Nuclear magnetic resonance

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  • Chemistry(all)

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A new family of platinum(ii) complexes incorporating five-and six-membered cyclic phosphine ligands. / Kerényi, Andrea; Kovács, Viktória; Körtvélyesi, T.; Ludányi, K.; Drahos, L.; Keglevich, G.

In: Heteroatom Chemistry, Vol. 21, No. 2, 2010, p. 63-70.

Research output: Contribution to journalArticle

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