A Mechanism for Dynamical Behavior in the Landolt Reaction with Ferrocyanide

Elizabeth C. Edblom, Laszlo Gyorgyi, Miklos Orban, Irving R. Epstein

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

A mechanism consisting of 13 elementary steps is proposed for the reaction of iodate, sulfite, and ferrocyanide. Computer simulations with the mechanism give excellent agreement with experimental observations of the batch behavior of both the component Landolt (iodate-sulfite) and the full system and with the bistability and oscillation found with the full system in a stirred tank reactor.

Original languageEnglish
Pages (from-to)4876-4880
Number of pages5
JournalJournal of the American Chemical Society
Volume109
Issue number16
DOIs
Publication statusPublished - Aug 1 1987

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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