A heme-like, water-soluble iron(II) porphyrin: Thermal and photoinduced properties, evidence for sitting-atop structure

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Abstract

Water-soluble ferrous porphyrin (FeIITPPS) was prepared by complexation reaction of free base porphyrin (H2TPPS) with iron(II) ions in the presence of iron(III)-trapping acetate buffer; the catalytic and photoinduced properties of this air-stable complex proved unambiguously its sitting-atop structure.

Original languageEnglish
Pages (from-to)224-226
Number of pages3
JournalChemical Communications
Issue number2
DOIs
Publication statusPublished - Jan 14 2005

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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