A direct approach to selective sulfonation of triarylphosphines

Henrik Gulyás, Áron Szöllosy, Brian E. Hanson, József Bakos

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

A practical and convenient synthesis of mono-, di- and a trisulfonated phosphines from triphenylphosphine analogs, (2,4-dimethylphenyl)3-n-(phenyl)n-phosphine and (4-methoxyphenyl)3-n-(phenyl)n-phosphine (n=0-2), is described, respectively. This represents an easy way to prepare water-soluble phosphines with complete selectivity, and with essentially no phosphine oxide formation.

Original languageEnglish
Pages (from-to)2543-2546
Number of pages4
JournalTetrahedron Letters
Volume43
Issue number14
DOIs
Publication statusPublished - Apr 1 2002

Keywords

  • Phosphines
  • Sulfonation
  • Water-soluble

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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