A comparative study of the complete oxidation of dimethyl ether on supported group VIII metals

F. Solymosi, J. Cserényi, L. Óvári

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

In the study of the interaction of dimethyl ether with alumina-supported platinum metals by means of infrared spectroscopy, methoxy species bonded to the alumina and CO adsorbed on the metals have been detected. The complete oxidation of dimethyl ether in a flow system sets in above 400 K and proceeded to 100% conversion at ∼ 673 K. No or only very slight deactivation was observed in 5 h. The specific activity order of the catalysts is: Ru > Pt > Ir > Pd > Rh.

Original languageEnglish
Pages (from-to)89-93
Number of pages5
JournalCatalysis Letters
Volume44
Issue number1-2
Publication statusPublished - 1997

Fingerprint

Aluminum Oxide
Ethers
ethers
Alumina
aluminum oxides
Metals
Platinum metals
Oxidation
oxidation
Carbon Monoxide
deactivation
metals
Infrared spectroscopy
platinum
infrared spectroscopy
catalysts
Catalysts
interactions
dimethyl ether

Keywords

  • Deactivation of catalysts
  • Decomposition of dimethyl ether
  • Dimethyl ether as an alternative fuel
  • Environmental catalysis
  • Formation of adsorbed CO
  • Infrared spectra of adsorbed dimethyl ether
  • Oxidation of dimethyl ether
  • Supported platinum catalysts

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

A comparative study of the complete oxidation of dimethyl ether on supported group VIII metals. / Solymosi, F.; Cserényi, J.; Óvári, L.

In: Catalysis Letters, Vol. 44, No. 1-2, 1997, p. 89-93.

Research output: Contribution to journalArticle

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