8.6 Physical Separations: Behavior of Structurally Similar Molecules in the Resolution Processes

Research output: Chapter in Book/Report/Conference proceedingChapter

8 Citations (Scopus)

Abstract

The resolution of racemic compounds with structurally similar resolving agents is examined. Summarizing experimental results, it can be established that the SDE (self-disproportionation of enantiomers) characteristic for the mixture of enantiomers of the racemic compound determines the results of the separations of the enantiomeric mixtures and the diastereomers. In addition, SDE influences the behavior of diastereomers obtained.

Original languageEnglish
Title of host publicationComprehensive Chirality
PublisherElsevier Ltd
Pages91-95
Number of pages5
Volume8
ISBN (Print)9780080951683
DOIs
Publication statusPublished - Sep 1 2012

Keywords

  • Chiral and achiral similar structures
  • Enantiomeric mixtures
  • Purity of enantiomers
  • Quasi conglomerate and racemate behavior
  • Resolution
  • Resolvability
  • Self-disproportionation

ASJC Scopus subject areas

  • Chemistry(all)

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