Foszfortartalmú heterociklusok gyurutranszformációi, XVI

Translated title of the contribution: 6,6-Diklór-3-foszfabiciklo[3.1.0]hexán-3-oxidok hidrogénezési reakcióinak vizsgálata

Keglevich György, Novák Tibor, Tungler Antal És, Toke László

Research output: Contribution to journalArticle

Abstract

Ring transformation of phosphorus containing heterocycles, XVI. Study of the hydrogenation reactions of 6,6-dichloro-3-phosphabicyclo[3.1.0]hexane 3-oxides. 1,2,3,4,5,6-Hexahydrophosphinine 1-oxides are obtained in good yields by the catalytic hydrogenation of the title compounds carried out at 85-90°C and 9 bar in the presence of 2 mol equivalents of triethylamine. Hydrogenation in the presence of diethylamine leads to a reasonable portion of the corresponding monochlorophosphabicyclohexane oxide beside the hexahydrophosphinine oxide.

Translated title of the contribution6,6-Diklór-3-foszfabiciklo[3.1.0]hexán-3-oxidok hidrogénezési reakcióinak vizsgálata
Original languageHungarian
Pages (from-to)217-221
Number of pages5
JournalMagyar Kemiai Folyoirat, Kemiai Kozlemenyek
Volume104
Issue number5
Publication statusPublished - Dec 1 1998

ASJC Scopus subject areas

  • Chemistry(all)

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