3-Phosphabicyclo[3.1.0]hexane 3-oxides: Useful intermediates for dihydro-, tetrahydro-and hexahydrophosphinines and phosphinines

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Abstract

3-Phosphabicyclo[3.1.0]hexane 3-oxides obtained from 2,5-dihydro-1H-phosphole oxides by the addition of dichlorocarbene are versatile intermediates for di-, tetra-and hexahydrophosphinine oxides, as well as phosphinines. Functionalization of the P-oxides is a suitable method for the preparation of phosphinic derivatives, P-sulfides and phosphine-boranes.

Original languageEnglish
Pages (from-to)119-136
Number of pages18
JournalReviews on Heteroatom Chemistry
Volume14
Publication statusPublished - 1996

Fingerprint

Hexanes
Oxides
phosphine
Boranes
Sulfides
Derivatives
phosphinine

Keywords

  • Functionalization
  • Phosphinine derivatives
  • Ring enlargement
  • Six-membered p-heterocycles

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

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abstract = "3-Phosphabicyclo[3.1.0]hexane 3-oxides obtained from 2,5-dihydro-1H-phosphole oxides by the addition of dichlorocarbene are versatile intermediates for di-, tetra-and hexahydrophosphinine oxides, as well as phosphinines. Functionalization of the P-oxides is a suitable method for the preparation of phosphinic derivatives, P-sulfides and phosphine-boranes.",
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issn = "0915-6151",
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N2 - 3-Phosphabicyclo[3.1.0]hexane 3-oxides obtained from 2,5-dihydro-1H-phosphole oxides by the addition of dichlorocarbene are versatile intermediates for di-, tetra-and hexahydrophosphinine oxides, as well as phosphinines. Functionalization of the P-oxides is a suitable method for the preparation of phosphinic derivatives, P-sulfides and phosphine-boranes.

AB - 3-Phosphabicyclo[3.1.0]hexane 3-oxides obtained from 2,5-dihydro-1H-phosphole oxides by the addition of dichlorocarbene are versatile intermediates for di-, tetra-and hexahydrophosphinine oxides, as well as phosphinines. Functionalization of the P-oxides is a suitable method for the preparation of phosphinic derivatives, P-sulfides and phosphine-boranes.

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KW - Phosphinine derivatives

KW - Ring enlargement

KW - Six-membered p-heterocycles

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