2-Aryl-dibenzo-1,2-oxaphosphorine as a ligand in borane and in Pt(II) complexes

György Keglevich, Helga Szelke, Andrea Kerényi, Tímea Imre, Krisztina Ludányi, József Dukai, Ferenc Nagy, Péter Arányi

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Optimum conditions for the synthesis of aryl-dibenzo-oxaphosphorines (2) from the corresponding phosphonous chloride (1) were explored to avoid the formation of by-products (e.g., 4-6). The aryl-dibenzo-oxaphosphorines (2) were converted to the P-oxides (3), and were utilized in the synthesis of phosphinite-boranes 7 and Pt(II) complexes 8. Depending on the aryl substituent, the Pt(II) complex (8) was formed with cis and trans geometry.

Original languageEnglish
Pages (from-to)459-463
Number of pages5
JournalHeteroatom Chemistry
Volume15
Issue number6
DOIs
Publication statusPublished - Nov 2 2004

ASJC Scopus subject areas

  • Chemistry(all)

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