1,7-Electrocyclization reactions of stabilized α,β: γ,δ-unsaturated azomethine ylides

J. Tóth, András Dancsó, Gábor Blaskó, L. Tőke, Paul W. Groundwater, Miklós Nyerges

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Stabilized α,β:γ,δ-unsaturated azomethine ylides were generated by the deprotonation of isoquinolinium salts. 1,7-Electrocyclization of these dipoles, followed by a 1,5-hydrogen shift, gives tetrahydro[5,6]azepino[2,1-a]isoquinolines.

Original languageEnglish
Pages (from-to)5725-5735
Number of pages11
JournalTetrahedron
Volume62
Issue number24
DOIs
Publication statusPublished - Jun 12 2006

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Isoquinolines
Deprotonation
Hydrogen
Salts
azomethine

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

1,7-Electrocyclization reactions of stabilized α,β : γ,δ-unsaturated azomethine ylides. / Tóth, J.; Dancsó, András; Blaskó, Gábor; Tőke, L.; Groundwater, Paul W.; Nyerges, Miklós.

In: Tetrahedron, Vol. 62, No. 24, 12.06.2006, p. 5725-5735.

Research output: Contribution to journalArticle

Tóth, J. ; Dancsó, András ; Blaskó, Gábor ; Tőke, L. ; Groundwater, Paul W. ; Nyerges, Miklós. / 1,7-Electrocyclization reactions of stabilized α,β : γ,δ-unsaturated azomethine ylides. In: Tetrahedron. 2006 ; Vol. 62, No. 24. pp. 5725-5735.
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