1,4-Dihydroxyoctaphenyltetrasilane, a stable polysilane-α,ω-diol

L. Párkányí, H. Stüger, E. Hengge

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

1,4-Dihydroxyoctaphenyltetrasilane is obtained in 60% yield by treating a solution of 1,4-dichlorooctaphenyltetrasilane in THF with dilute HCl. Spectroscopic properties of the title compound are reported together with an X-ray structure determination, which shows that there is an intramolecular hydrogen bond between the 2 OH groups. This structural feature accounts for the ease with which the compound loses water to form the heterocyclic siloxane octaphenyloxacyclopentasilane.

Original languageEnglish
Pages (from-to)187-192
Number of pages6
JournalJournal of Organometallic Chemistry
Volume333
Issue number2
DOIs
Publication statusPublished - Oct 20 1987

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Polysilanes
Siloxanes
polysilanes
siloxanes
Hydrogen
Hydrogen bonds
X-Rays
hydrogen bonds
X rays
Water
water
x rays

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

1,4-Dihydroxyoctaphenyltetrasilane, a stable polysilane-α,ω-diol. / Párkányí, L.; Stüger, H.; Hengge, E.

In: Journal of Organometallic Chemistry, Vol. 333, No. 2, 20.10.1987, p. 187-192.

Research output: Contribution to journalArticle

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