1,4-Additions of tricyclic 1,4-diphosphinines-a novel system to study σ-bond activation and π-π Dispersion interactions

Abhishek Koner, Zsolt Kelemen, Gregor Schnakenburg, László Nyulászi, Rainer Streubel

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The dienic nature of the aromatic π-system in 1,4-diphosphinines remains largely unexplored to this day due to a lack of facile and efficient synthetic protocols. Recently reported stable, tricyclic 1,4-diphosphinines were used to explore the thermal reactivity of the π-system towards an array of dienophiles in [4π+2π]- and, for the first time, in [4π+2σ]-type cycloaddition reactions.

Original languageEnglish
Pages (from-to)1182-1184
Number of pages3
JournalChemical Communications
Volume54
Issue number10
DOIs
Publication statusPublished - Jan 1 2018

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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