1,4-Additions of tricyclic 1,4-diphosphinines-a novel system to study σ-bond activation and π-π Dispersion interactions

Abhishek Koner, Zsolt Kelemen, Gregor Schnakenburg, L. Nyulászi, Rainer Streubel

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The dienic nature of the aromatic π-system in 1,4-diphosphinines remains largely unexplored to this day due to a lack of facile and efficient synthetic protocols. Recently reported stable, tricyclic 1,4-diphosphinines were used to explore the thermal reactivity of the π-system towards an array of dienophiles in [4π+2π]- and, for the first time, in [4π+2σ]-type cycloaddition reactions.

Original languageEnglish
Pages (from-to)1182-1184
Number of pages3
JournalChemical Communications
Volume54
Issue number10
DOIs
Publication statusPublished - Jan 1 2018

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Cycloaddition
Chemical activation
Hot Temperature

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

1,4-Additions of tricyclic 1,4-diphosphinines-a novel system to study σ-bond activation and π-π Dispersion interactions. / Koner, Abhishek; Kelemen, Zsolt; Schnakenburg, Gregor; Nyulászi, L.; Streubel, Rainer.

In: Chemical Communications, Vol. 54, No. 10, 01.01.2018, p. 1182-1184.

Research output: Contribution to journalArticle

Koner, Abhishek ; Kelemen, Zsolt ; Schnakenburg, Gregor ; Nyulászi, L. ; Streubel, Rainer. / 1,4-Additions of tricyclic 1,4-diphosphinines-a novel system to study σ-bond activation and π-π Dispersion interactions. In: Chemical Communications. 2018 ; Vol. 54, No. 10. pp. 1182-1184.
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