1,3- And 1,5-migrations involving chlorine

L. Tőke, Zoltán Bende, I. Bitter, Gábor Tóth, Pál Simon, Rudolf Sos

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Rearrangement processes involving chlorine have been observed in the reaction of l,l,l-trichloro-2-hydroxy-4-miethyl- petene-3(1) with inorganic acid chlorides. Conversion of compound 2 to 3 represent a new example of a 1,3-chlorine shift. Formation of compound 4 from 6 is a new type of rearrangement involving 1,5-chlorine migration, and at the same time, is a good example of the role of kinetic vs. thermodinamic control in chemical processes. The transformations were found to proceed via radical intermediates.

Original languageEnglish
Pages (from-to)4507-4511
Number of pages5
JournalTetrahedron
Volume40
Issue number21
DOIs
Publication statusPublished - 1984

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Chlorine
Chemical Phenomena
Inorganic acids
Chlorides
Kinetics
Acids

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

1,3- And 1,5-migrations involving chlorine. / Tőke, L.; Bende, Zoltán; Bitter, I.; Tóth, Gábor; Simon, Pál; Sos, Rudolf.

In: Tetrahedron, Vol. 40, No. 21, 1984, p. 4507-4511.

Research output: Contribution to journalArticle

Tőke, L, Bende, Z, Bitter, I, Tóth, G, Simon, P & Sos, R 1984, '1,3- And 1,5-migrations involving chlorine', Tetrahedron, vol. 40, no. 21, pp. 4507-4511. https://doi.org/10.1016/S0040-4020(01)98827-1
Tőke, L. ; Bende, Zoltán ; Bitter, I. ; Tóth, Gábor ; Simon, Pál ; Sos, Rudolf. / 1,3- And 1,5-migrations involving chlorine. In: Tetrahedron. 1984 ; Vol. 40, No. 21. pp. 4507-4511.
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AU - Sos, Rudolf

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