1,3- And 1,5-migrations involving chlorine

László Töke, Zoltán Bende, István Bitter, Gábor Tóth, Pál Simon, Rudolf Sos

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Rearrangement processes involving chlorine have been observed in the reaction of l,l,l-trichloro-2-hydroxy-4-miethyl- petene-3(1) with inorganic acid chlorides. Conversion of compound 2 to 3 represent a new example of a 1,3-chlorine shift. Formation of compound 4 from 6 is a new type of rearrangement involving 1,5-chlorine migration, and at the same time, is a good example of the role of kinetic vs. thermodinamic control in chemical processes. The transformations were found to proceed via radical intermediates.

Original languageEnglish
Pages (from-to)4507-4511
Number of pages5
JournalTetrahedron
Volume40
Issue number21
DOIs
Publication statusPublished - 1984

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ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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