1,2-Bond shift isomerization of oxiranes on copper-graphimet

Árpád Molnár, A. Mastalir, M. Bartók

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

2,2,3,3-Tetramethyloxirane (1) undergoes isomerization on copper intercalated graphite (graphimet) to t-butyl methyl ketone (4) via a 1,2-methyl migration and to 2,3-dimethylbut-3-en-2-ol (5) via a 1,3-hydrogen shift, as well as deoxygenation and dehydration products.

Original languageEnglish
Pages (from-to)124-126
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
Publication statusPublished - 1989

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Hexanones
Graphite
Epoxy Compounds
Isomerization
Ketones
Dehydration
Copper
Hydrogen

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

1,2-Bond shift isomerization of oxiranes on copper-graphimet. / Molnár, Árpád; Mastalir, A.; Bartók, M.

In: Journal of the Chemical Society, Chemical Communications, No. 2, 1989, p. 124-126.

Research output: Contribution to journalArticle

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