1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph 3SnP2C3Bu3t: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour

F. Geoffrey, N. Cloke, Peter B. Hitchcock, John F. Nixon, D. James Wilson, László Nyulászi, Tamás Kárpáti

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Abstract

The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.

Original languageEnglish
Pages (from-to)3983-3989
Number of pages7
JournalJournal of Organometallic Chemistry
Volume690
Issue number17
DOIs
Publication statusPublished - Sep 1 2005

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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