1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph 3SnP2C3Bu3t

Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour

F. Geoffrey, N. Cloke, Peter B. Hitchcock, John F. Nixon, D. James Wilson, L. Nyulászi, T. Kárpáti

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.

Original languageEnglish
Pages (from-to)3983-3989
Number of pages7
JournalJournal of Organometallic Chemistry
Volume690
Issue number17
DOIs
Publication statusPublished - Sep 1 2005

Fingerprint

Theoretical Models
Crystal structure
X-Rays
solid state
X rays
preparation
crystal structure
rings
shift
x rays

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

Cite this

1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph 3SnP2C3Bu3t : Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour. / Geoffrey, F.; Cloke, N.; Hitchcock, Peter B.; Nixon, John F.; Wilson, D. James; Nyulászi, L.; Kárpáti, T.

In: Journal of Organometallic Chemistry, Vol. 690, No. 17, 01.09.2005, p. 3983-3989.

Research output: Contribution to journalArticle

@article{fcc29b71264946509dcba8778fedb7de,
title = "1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph 3SnP2C3Bu3t: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour",
abstract = "The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.",
author = "F. Geoffrey and N. Cloke and Hitchcock, {Peter B.} and Nixon, {John F.} and Wilson, {D. James} and L. Nyul{\'a}szi and T. K{\'a}rp{\'a}ti",
year = "2005",
month = "9",
day = "1",
doi = "10.1016/j.jorganchem.2005.05.046",
language = "English",
volume = "690",
pages = "3983--3989",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "17",

}

TY - JOUR

T1 - 1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph 3SnP2C3Bu3t

T2 - Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour

AU - Geoffrey, F.

AU - Cloke, N.

AU - Hitchcock, Peter B.

AU - Nixon, John F.

AU - Wilson, D. James

AU - Nyulászi, L.

AU - Kárpáti, T.

PY - 2005/9/1

Y1 - 2005/9/1

N2 - The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.

AB - The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.

UR - http://www.scopus.com/inward/record.url?scp=25144450865&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=25144450865&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2005.05.046

DO - 10.1016/j.jorganchem.2005.05.046

M3 - Article

VL - 690

SP - 3983

EP - 3989

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 17

ER -