Über die Struktur der Thioamide und ihrer Derivate-XXXVIII. Assoziationserscheinungen in Lösungen primärer Thioamide

Wolfgang Walter, Peter Vinkler

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11 Citations (Scopus)

Abstract

The i.r. stretching and bending frequencies of the NH2 group of thioacetamide, thiobenzamide and cyclohexane-carboxylic acid thioamide have been studied in polar and nonpolar solvents. In nonpolar media two selfassociated species occur with characteristic NH2 bending frequencies. In dichloromethane solutions of the thioamides in the presence of proton acceptors 1:1- and 2:1 complexes have been detected. The NH2 symmetric stretching vibration of the complexes split into a doublet due to Fermi resonance with the first overtone of the NH2 bending mode.

Original languageGerman
Pages (from-to)205-212
Number of pages8
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume33
Issue number2
DOIs
Publication statusPublished - 1977

ASJC Scopus subject areas

  • Engineering(all)

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